Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene

Nicka Chinkov; Anat Levin; Ilan Marek

doi:10.1002/anie.200501946

Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene

Nicka Chinkov, Anat Levin, Ilan Marek

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) From A to Z: Allylzirconocenes have been easily prepared in a one-pot procedure through a tandem allylic C-H activation-β-elimination reaction from unsaturated fatty alcohol and ether starting materials (see scheme). The reaction proceeds rapidly under mild condition and is insensitive to the length of the carbon tether between the double bond and the alcohol moiety.

Original language	English
Pages (from-to)	465-468
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	3
DOIs	https://doi.org/10.1002/anie.200501946
State	Published - 9 Jan 2006
Externally published	Yes

Keywords

Alcohols
Allylic compounds
C-H activation
Elimination
Zirconium

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200501946

Cite this

@article{e9270b7bd11d461ebeda07af4ca8cd22,

title = "Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene",

abstract = "(Chemical Equation Presented) From A to Z: Allylzirconocenes have been easily prepared in a one-pot procedure through a tandem allylic C-H activation-β-elimination reaction from unsaturated fatty alcohol and ether starting materials (see scheme). The reaction proceeds rapidly under mild condition and is insensitive to the length of the carbon tether between the double bond and the alcohol moiety.",

keywords = "Alcohols, Allylic compounds, C-H activation, Elimination, Zirconium",

author = "Nicka Chinkov and Anat Levin and Ilan Marek",

year = "2006",

month = jan,

day = "9",

doi = "10.1002/anie.200501946",

language = "English",

volume = "45",

pages = "465--468",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "3",

}

TY - JOUR

T1 - Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene

AU - Chinkov, Nicka

AU - Levin, Anat

AU - Marek, Ilan

PY - 2006/1/9

Y1 - 2006/1/9

N2 - (Chemical Equation Presented) From A to Z: Allylzirconocenes have been easily prepared in a one-pot procedure through a tandem allylic C-H activation-β-elimination reaction from unsaturated fatty alcohol and ether starting materials (see scheme). The reaction proceeds rapidly under mild condition and is insensitive to the length of the carbon tether between the double bond and the alcohol moiety.

AB - (Chemical Equation Presented) From A to Z: Allylzirconocenes have been easily prepared in a one-pot procedure through a tandem allylic C-H activation-β-elimination reaction from unsaturated fatty alcohol and ether starting materials (see scheme). The reaction proceeds rapidly under mild condition and is insensitive to the length of the carbon tether between the double bond and the alcohol moiety.

KW - Alcohols

KW - Allylic compounds

KW - C-H activation

KW - Elimination

KW - Zirconium

UR - http://www.scopus.com/inward/record.url?scp=30444439065&partnerID=8YFLogxK

U2 - 10.1002/anie.200501946

DO - 10.1002/anie.200501946

M3 - Article

C2 - 16342305

AN - SCOPUS:30444439065

SN - 1433-7851

VL - 45

SP - 465

EP - 468

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 3

ER -

Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this