Unsaturated fatty alcohol derivatives as a source of substituted allylzirconocene

Nicka Chinkov, Anat Levin, Ilan Marek

Research output: Contribution to journalArticlepeer-review

Abstract

(Chemical Equation Presented) From A to Z: Allylzirconocenes have been easily prepared in a one-pot procedure through a tandem allylic C-H activation-β-elimination reaction from unsaturated fatty alcohol and ether starting materials (see scheme). The reaction proceeds rapidly under mild condition and is insensitive to the length of the carbon tether between the double bond and the alcohol moiety.

Original languageEnglish
Pages (from-to)465-468
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number3
DOIs
StatePublished - 9 Jan 2006
Externally publishedYes

Keywords

  • Alcohols
  • Allylic compounds
  • C-H activation
  • Elimination
  • Zirconium

ASJC Scopus subject areas

  • General Chemistry
  • Catalysis

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