New approach to the stereoselective synthesis of metalated dienes via an isomerization-elimination sequence

Nicka Chinkov, Swapan Majumdar, Ilan Marek

Research output: Contribution to journalArticlepeer-review

Abstract

Treatment of Cp2ZrBu2 with enol ether containing a remote double bond lead to conjugated metalated diene as single isomer via a tandem isomerization-elimination sequence. 2-Arylsulfonyl 1,3-dienes can also be used as a source of dienyl zirconocene derivatives, and the stereochemistry of the diene is dependent on the transmetalation reaction.

Original languageEnglish
Pages (from-to)10282-10283
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number35
DOIs
StatePublished - 4 Sep 2002
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • Biochemistry
  • Catalysis
  • Colloid and Surface Chemistry

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