A zirconium promenade - An efficient tool in organic synthesis

Ilan Marek; Nicka Chinkov; Anat Levin

doi:10.1055/s-2006-932483

A zirconium promenade - An efficient tool in organic synthesis

Ilan Marek, Nicka Chinkov, Anat Levin

Research output: Contribution to journal › Article › peer-review

Abstract

The one-pot preparation of allyl- and dienyl-zirconocene derivatives can be easily achieved via a tandem allylic C-H-activation-β-elimination reaction from unsaturated fatty alcohol and enol ether derivatives, respectively. The reaction proceeds rapidly, under mild conditions, and is insensitive to the length of the carbon tether between the double bond and the leaving group moiety.

Original language	English
Pages (from-to)	501-514
Number of pages	14
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-2006-932483
State	Published - 2 Mar 2006
Externally published	Yes

Keywords

Allylic C-H activation
Allylzirconocene
Dienyl zirconocene
Elimination
Isomerization

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-2006-932483

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title = "A zirconium promenade - An efficient tool in organic synthesis",

abstract = "The one-pot preparation of allyl- and dienyl-zirconocene derivatives can be easily achieved via a tandem allylic C-H-activation-β-elimination reaction from unsaturated fatty alcohol and enol ether derivatives, respectively. The reaction proceeds rapidly, under mild conditions, and is insensitive to the length of the carbon tether between the double bond and the leaving group moiety.",

keywords = "Allylic C-H activation, Allylzirconocene, Dienyl zirconocene, Elimination, Isomerization",

author = "Ilan Marek and Nicka Chinkov and Anat Levin",

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AU - Marek, Ilan

AU - Chinkov, Nicka

AU - Levin, Anat

PY - 2006/3/2

Y1 - 2006/3/2

N2 - The one-pot preparation of allyl- and dienyl-zirconocene derivatives can be easily achieved via a tandem allylic C-H-activation-β-elimination reaction from unsaturated fatty alcohol and enol ether derivatives, respectively. The reaction proceeds rapidly, under mild conditions, and is insensitive to the length of the carbon tether between the double bond and the leaving group moiety.

AB - The one-pot preparation of allyl- and dienyl-zirconocene derivatives can be easily achieved via a tandem allylic C-H-activation-β-elimination reaction from unsaturated fatty alcohol and enol ether derivatives, respectively. The reaction proceeds rapidly, under mild conditions, and is insensitive to the length of the carbon tether between the double bond and the leaving group moiety.

KW - Allylic C-H activation

KW - Allylzirconocene

KW - Dienyl zirconocene

KW - Elimination

KW - Isomerization

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DO - 10.1055/s-2006-932483

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SP - 501

EP - 514

JO - Synlett

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ER -

A zirconium promenade - An efficient tool in organic synthesis

Abstract

Keywords

ASJC Scopus subject areas

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